2017-09-18 07:54:22
Label: msds
Part 1 I. Chemical and company identification should indicate the name of the chemical, which should be the same as the name on the safety label, and it is recommended that the supplier's product code should be indicated as well.
The supplier's name, address, telephone number, emergency number, fax and e-mail address should be indicated. The section should also state the recommended and restricted uses of the chemical.
Part 2 - Hazard Summary
This section should contain information on the chemical's main physical and chemical hazards, as well as information on its effects on human health and the environment, and, if there are any special hazardous properties of the chemical, they should also be stated here. If the chemical has been classified according to GHS, the GHS hazard class should be indicated, and GHS labeling elements such as pictograms or symbols, precautionary statements, hazard information and warning words should be indicated. Pictograms or symbols such as flames, skeletons, and crossbones may be shown in black and white, and hazards not covered by the GHS classification (e.g., dust explosion hazards) should also be indicated here. The main symptoms of personnel exposure and an overview of the emergency response should be noted.
Part 3 - Composition/Composition Information
This section should indicate whether the chemical is a substance or a mixture. If it is a substance, the chemical or common name, the American Chemical Abstracts Registry number (CAS number) and other identifiers should be provided. If a substance is classified as a hazardous chemical according to the GHS classification criteria, the chemical or common name, and the concentration or concentration range of all hazardous components, including impurities and stabilizers, that affect the hazard classification of the substance should be listed. In the case of a mixture, it is not necessary to list all components.
If a component is classified as hazardous according to the GHS criteria and is present at a level above the concentration limit, name information, concentration or concentration range of the component should be listed. For components that have been identified as hazardous, the chemical or common name, concentration or concentration range of those components identified as hazardous should also be provided.
Part 4 First Aid Measures
This part should describe the first aid measures to be taken and actions to be avoided, if necessary, and should be completed in a manner that can be easily understood by the victim and/or the rescuer.
Subdivide the information according to the different modes of exposure: inhalation, skin contact, eye contact and ingestion. This section should provide a brief description of the acute and delayed effects, major symptoms and major health effects of exposure to the chemical,
Detailed information may be included in Part 11. If necessary, this item should include advice on the protection of the rescuer and special instructions for the physician. If necessary, prompt medical attention and special treatment should also be given.
Part 5 I I Fire Fighting Measures
This part should indicate suitable methods and agents for extinguishing fires, and unsuitable extinguishing agents, if any, should also be indicated here. The special hazards of the chemical should be indicated (e.g. the product is dangerously flammable). Mark the special fire extinguishing methods and protection of firefighters special protective equipment.
Part 6 - Emergency response to spills
This part should include the following information:
Operator protection, protective equipment and emergency response procedures.
-Environmental protection measures.
Sheltering of spilled chemicals, methods of removal, and disposal materials used (if different from Part 13, list recovery, neutralization, and removal methods).
I Provide precautions to prevent secondary hazards from occurring.
Part 7 I Operational Disposal and Storage
Operational disposal should describe safe disposal precautions, including technical measures to prevent human contact with the chemical, to prevent the occurrence of fires and explosions, and to provide localized or general ventilation, and to prevent the formation of aerosols and dusts. Special handling precautions to prevent direct contact with incompatible substances or mixtures should also be included.
Storage should describe the conditions for safe storage (suitable and unsuitable storage conditions), technical safety measures, measures for segregation of storage from prohibited substances, and information on packaging materials (recommended and non-recommended packaging materials).
Part 8 Exposure Controls and Individual Protection
Specify permissible concentrations, such as occupational exposure limits or biological limits. List engineering control methods to reduce exposure, this information is in addition to the content of Part 7. If possible, list the date of publication of the tolerable concentration, the source of the data, the test method, and the source of the method. List recommended personal protective equipment (PPE).
For example:
I Respiratory protection;
-Hand protection;
-Eye protection;
-Skin and body protection. Identify the type and material of protective equipment. Chemicals that are dangerous only under certain special conditions, such as large quantities, high concentrations, high temperatures, high pressures, etc., should be labeled with special protective measures for these situations.
Part 9 I Physical and Chemical Properties
This part should provide the following information:
-Appearance and properties of the chemical, such as:
Physical form, shape, and color;
Odor;
PH value, and indicate the concentration;
Melting/freezing point. -Melting/freezing point;
-Boiling point, initial boiling point and boiling range;
-Flash point;
-Combustion upper and lower limits or explosion limits;
-Vapor pressure
-vapor density;
-density/relative density;
-solubility;
-n-octanol/water partition coefficient;
-white ignition temperature;
-Decomposition temperature;
-The following information should be provided if necessary:
-Odor threshold;
-Evaporation rate;
-Flammability (solid, gas).
Other information on the safe use of the chemical, such as radioactivity or bulk density, should also be provided. SI International System of Units (SI) units should be used, see ISO1000:1992 and ISO1000:1992/Amd1:1998. non-SI bits may be used, but only as a supplement to SI units. Where necessary, the method of determination of the data shall be provided.
Part 10 I I Stability and Reactivity
This part shall describe the stability of the chemical and the hazardous reactions that may occur under specific conditions. The following information should be included:
-Conditions to be avoided (e.g., static electricity, impact, or vibration);
-Incompatible substances;
-Hazardous decomposition products, except for carbon monoxide, carbon dioxide, and water.
Completion of this section should take into account the intended use and foreseeable misuse of the chemical provided.
Part 11 I Toxicological Information
This section should provide a comprehensive and concise description of the various toxicological effects (health effects) that result from the user's exposure to the chemical. The following information should be included:
-Acute toxicity;
-Skin irritation or corrosion;
-Eye irritation or corrosion;
-Respiratory or skin sensitization;
-Germ cell mutagenicity;
-Carcinogenicity;
-Reproductive toxicity;
-Specific target organ systemic toxicity
A single exposure;
-specific target organ system toxicity
a repeated exposure;
-inhalation hazard.
The following information may also be provided:
-Toxicokinetic, metabolic and distribution information. Note:In vitro mutagenicity test data, such as Ames test data, are described in the Germ Cell Mutagenesis entry. If possible, describe toxic effects resulting from a single exposure, repeated exposure versus continuous exposure; delayed and immediate effects should be described separately.
Potentially harmful effects should include symptoms, physicochemical and toxicological properties related to those observed in tests with toxicity values (e.g. acute toxicity estimates). Information should be provided according to the different routes of exposure (e.g. inhalation, dermal contact, eye contact, ingestion). If possible, provide additional data or results from scientific experiments and cite literature sources. If the mixture has not been tested for toxicity as a whole, provide information on each component.
Part 12 I Ecological Information
This part provides information on the environmental impacts, environmental behavior and fate of the chemical, such as: expected behavior of the chemical in the environment, possible environmental impacts/ecotoxicity; - persistence and degradability; - potential bioaccumulation; - transport in soil. Mobility in soil. If possible, provide additional data or results generated by scientific experiments and cite literature sources. If possible, provide any ecological limit values.
Part 13 I Waste Disposal
This part includes information on recommended methods of waste disposal that are safe and beneficial to the environment. These disposal methods apply to the chemical (residual waste) as well as to any contaminated containers and packaging. Downstream users are reminded of local waste disposal regulations.
Part 14 Transportation Information
This part includes information on numbering and classification under international transportation regulations, which should be differentiated according to the different modes of transport, e.g. land, sea and air. The following information should be included: - UN Dangerous Goods Number (UN No.); - UN Transportation Name; - UN Hazard Classification; - Packing Group (if possible); and I Marine Pollutant (Yes/No). -Provide other special precautions related to the transport or means of transport that the user needs to know or observe. Provisions of other relevant legislation may be added.16 Part 15 I I Regulatory information
This part should indicate the name of the legislation governing the chemical in the country or region where this SDS is used. Provide regulatory information and chemical labeling information as it relates to the law. Remind downstream users of local waste disposal regulations,
Part 16-Other Information
This section should further provide other important information not covered in the above items. For example, specialized training required, recommended uses and restricted uses may be provided. References may be listed in this section.