B, healthy people's saliva contains salivary amylase, which belongs to protein, so the identification with biuret reagent can lead to purple reaction, B error;
C, healthy people's gastric juice contains pepsin, which belongs to protein, so biuret reagent can be used to identify purple reaction, C error;
D, healthy urine contains urea, inorganic salts, etc. , and does not contain protein, biuret reagent identification can't have purple reaction, D is correct.
Therefore, choose: d.