Is 99 sunny an idiom?

Not an idiom.

The sunny day in September is not an idiom, but a word to describe the sunny day in spring. The sunny day in September means that every nine days from the winter solstice is September 19, and counting the ninth September, it is already a "shocking" season full of spring, that is, when the sun is shining, it is spring. This word is often used to describe the sunny and warm climate in spring.